Explanation:

- Option 1: Chisel : Sculptor

- A sculptor uses a chisel as a tool for their work.

- Option 2: Anvil : Blacksmith

- A blacksmith uses an anvil as a tool or apparatus to shape metal.

- Option 3: Paper : Book

- A book is made from paper, but paper is not a tool for making a book.

- This pair doesn't directly reflect a tool and user relationship.

- Option 4: Scalpel : Surgeon

- A surgeon uses a scalpel as a tool for performing surgeries.

- The first, second, and fourth options are tool and user relationships. The third one is a material-to-product relationship.

Option 3: Paper : Book is the odd one out.

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