Explanation:

• The largest source of Sulfur Dioxide (SO2) in the atmosphere is the burning of fossil fuels by power plants and other industrial facilities. Smaller sources of SO2 emissions include: industrial processes such as extracting metal from ore; natural sources such as volcanoes; and locomotives, ships and other vehicles and heavy equipment that burn fuel with a high sulfur content.
• SO2 emissions that lead to high concentrations of SO2 in the air generally also lead to the formation of other sulfur oxides (SOx). SOx can react with other compounds in the atmosphere to form small particles. These particles contribute to particulate matter (PM) pollution.

Hence only statement 2nd is correct.